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  • Features of the ruthenium oxide-titanium anodes in sodium chloride solutions of different concentrations

    The effect of sodium chloride concentration on the job ORTA electrodes. It is found that the electrodes OPTA, especially in the sodium chloride concentration below 50 g/liter, three groups occur conjugate processes, oxidation of chloride ions, the solid-phase oxidation of the anode material, dissolution of the active catalytic coating. The processes of oxidation of chloride ions prevail in current densities of 0.001 - 0.032 A/cm2 at high current densities become essential processes of oxidation of the ruthenium oxide coating. The oxidation of chloride ions, especially at concentrations less than 50 g/liter can be described as occurring in a constantly evolving anode active material due to its corrosion and solid-phase oxidation.

    Keywords: ruthenium oxide-titanium anode, sodium hypochlorite, polarization dependence, water disinfection, tafel dependence, oxidation of chloride ions, solid-phase oxidation of the anode material, changes in the activity of the anode material, anion ruthenate, an