Физические свойства многокомпонентных узкозонных твердых растворов с мезоструктурой

Благин А.В.; Благина Л.В.; Кодин В.В.; Нефедова Н.А.; Попова И.Г.

Physical properties of multicomponent narrow-gap solid solutions with mesostructure authors

Blagin A.V., Blagina L.V., Kodin V.V., Nefedova N.A., Popova I.G.

Incoming article date: 28.03.2018

In this paper, the modeling of phase equilibria in multicomponent systems of A3B5 compounds was carried out and the compositions of the liquid phase equilibrated with a given solid solution were calculated. A model of excess thermodynamic functions is used, which takes into account the formation of associates in the melt near the solidus temperatures. The developed algorithm allows solving a direct problem (in which the input parameters are the growth temperature of the layers and the composition of the solid phase corresponding to the expected instrument characteristics) and the inverse problem (the growth temperature and composition of the solid solution are sought for the given liquid phase). The limiting concentrations of the alloying components, arsenic and bismuth, are determined. The structural and electrophysical characteristics of multicomponent semiconductor A3B5 heterosystems are discussed, the solid solutions of which crystallize from the liquid phase in a gradient thermal field. The mechanism for introducing impurities into the lattice of epitaxial layers of multicomponent solid solutions is described for the first time. With an increase in the thickness of the crystallizable film, the thermodynamically equilibrium substitution by antimony bismuth atoms is completed and the introduction of Bi atoms into the interstices takes place. The interaction of neighboring atoms with the valence electron shells of Bi becomes more symmetrical, which causes an increase in concentration. The concentration of film defects near its rear surface also increases. The obtained values of electrophysical parameters make it possible to draw a conclusion about the instrumental suitability of the materials under study.

Keywords: solid solutions, mesostructure, antimonide, alloying, liquid phase, phase transformations, binary compounds, associates, lattice constant, multicomponent systems