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The use of ethyl silicates to improve the waterproofing properties of structures for soil and concrete construction building

Abstract

The use of ethyl silicates to improve the waterproofing properties of structures for soil and concrete construction building

Vasilovskaya G., Druzhinkin S., Peresypkin E., Berseneva M.

Incoming article date: 10.04.2023

The study findings on the utilization of ethyl silicates for enhancing bitumen properties are showcased. The impact of ethyl silicate grades 28, 32, and 40 on the characteristics of BN 90/10, BN 70/30 construction bitumen, and BND 60/90 road bitumen was evaluated. On the basis of the conducted studies, grades of bitumen and ethyl silicate were selected, the compositions based on which have the best performance. The compatibility of ethyl silicates with bitumen was tested. It has been established that a smaller amount of ethyl silicate is combined with high-quality bitumen. Based on the infra-red spectra, it was shown that there is no chemical interaction between bitumen and ethyl silicate, but a hydrolysis reaction occurs with the formation of hydrogen bonds. It has moreover been determined that ethyl silicates exhibit both plasticizing and structuring effects on bitumen, resulting in improved frost resistance of polymer-bitumen compositions. Requirements for materials aimed at waterproofing of structures for soil and concrete constructions have been developed and presented. In order to increase the low-temperature limit of applicability of polymer bitumen compositions, additives of liquid oligomeric rubbers from the Yaroslavl synthetic rubber plant (SK-1), as well as latexes from the Krasnoyarsk and Omsk plants were studied together with ethyl silicates. Recommendations are given on the use of ethyl silicates in waterproofing mastics and asphalt polymer concrete.

Keywords: bitumen, ethyl silicates, compatibility, properties, plasticizing and structuring additives, waterproofing mastics, asphalt polymer concrete, IR spectra, soil and concrete structures