Piezoceramics phases of (1-х)PbTiO3-xPbZrO3 is the basis of most high-performance piezoelectric materials. Electrophysical and mechanical properties of these materials can be varied over a wide range by varying the composition and by processing methods: the methods and modes of sintering conditions polarization. Topical to study the influence on the properties of PZT materials processing methods at the stages of manufacturing piezoelectric samples. In the role model of the object has been selected multicomponent system PbTiO3-PbZrO3-PbNb2/3Zn1/3O3-PbW1/2Mg1/2O3-PbSb2/3Mn1/3O3. Samples of piezoelectric elements for the study were obtained in two ways: in the first case, the sintering samples was carried out by the usual ceramic technology, and in the second by hot pressing. The grain structure was formed in both cases in the presence of the glass phase, the quantity of which decreases with increasing temperature, while in the first case, an increase in the velocity of the secondary recrystallization, and in the second of its suppression. It was found that regardless of the technology of the samples εT33/ε0, d33 and VЕ1 at high temperatures, due to the increase of grain and coercive field, which complicates the process of polarization. Maximum values εT33/ε0, d33 and VЕ1 samples prepared by hot pressing at 10 - 15% higher than if received by conventional ceramic technology.
Keywords: Piezoelectric ceramics, doping, combination, pezophase, piezomaterial
The problem of manufacturing technology heterostructures pezofaza - metal considered in the article. Complexity consists in the fact that during the removal of the polymer in the system at low temperatures are formed porous layers, formed powders separated metal layers, having island macrostructure. One way to solve the problem - reducing the firing temperature heterostructures. Proposed to decrease the sintering temperature by using of functionally active glass-phases. Reducing the sintering temperature of products also allows to replace platinum electrodes inexpensive silver-based alloys. Obtained by solid state reaction method of piezoceramic material has a low sintering temperature (980 ° C) and high electrical parameters. Found that not only the proportion of the vitreous mass, but also their qualitative influence on the properties of piezomaterials
Keywords: heterostructure glass phase, the sintering temperature, porosity, ferroelectric phase
Piezoelectric ceramics on the basis of the phase of (1-x) PbTiO3-xPbZrO3 is the basis of most high-performance piezoelectric materials. Electrophysical and mechanical properties of these materials can vary widely in different ways. Traditional methods include changes in composition within the morphotropic region and doping. Now is the study of the influence of topical makrolegirovaniya the material properties of the PZT system. As a model system was selected phase of the PZT system, the compositions of which MO belong, one of which contains a dopant in the sublattice (A) and another - in the sublattice dopants (B). The studies established that one of the effective ways of varying the parameters piezomaterials may be the formation of solid solutions on the basis of two or more piezoelectric phases having different combinations of electrical parameters
Keywords: Piezoelectric ceramics, doping, kombinorovanie, pezofaza, piezo