It is shown that to describe the phenomena and processes in a transition interfacial layer having a certain thickness, it is useful to distinguish the boundary layer of the surface and boundary diffusion layer, which lies entirely in the less condensed phase related. In accordance with this energy and power characteristics of the transition layer should be attributed to the boundary surface of the interphase transition layer. The basic equation of electro capillary boundary of the surface layer, establishing the dependence of the surface tension of this layer on the chemical composition of the second phase, and bordering the jump of electric potential between them.

Keywords: Interphase layer, Entropy, Concentration, Adsorption, Surface tension boundary layer, the surface energy, electrochemical electrode