Carbothermal synthesis method on substrates of a-Al2O3 thin film with sublayers ZnO: Ga, using copper as a catalyst for the arrays obtained by varying the zinc oxide rod morphology. It was established that growth of the rods occurs direction perpendicular to the substrate using a thin (~ 1 nm) layers of the catalyst. With increasing thickness of the catalyst layer to 3 nm rods growth occurs at an angle to the surface of the rod with a mutual orientation in the plane of the substrate surface at angles that are multiples of 60 °. Also, the selectivity demonstrated growth ZnO rods arrays on portions of the substrate coated with the catalyst.
Keywords: zinc oxide, micro - and nanorods carbothermic synthesis method, film sublayer growth catalyst.

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In the present work we have carried out studies of the processes of growth of zinc oxide nanorods by hydrothermal method on silicon substrates. As sublayer catalyst used growth caused by laser deposition of zinc oxide, various thicknesses. Studied selective growth of nanorods on the microstructure of thin-film sub-layers of zinc oxide obtained by laser deposition. The optimal conditions for the synthesis of: the concentration of Zn (NO3) 2 - 0.4 mol / l, hexamethylenetetramine - 0.4 mol / l, the concentration of NH3 · H2O - 0,01 mol / L -0.01, process time 4:00, the process temperature is 80 ° C. Sublayer thickness of zinc oxide, as shown by experiment, the growth of the rods has no noticeable effect. Oriented arrays of nanorods were obtained up to 500 nm and a diameter of 60-150 nm.
Keywords: zinc oxide nanorods and micro-oriented arrays of nanorods, hydrothermal synthesis method, selective growth, thin film underlayer.

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