The dispersion parameters of the active component of cobalt catalysts promoted by nickel for Fischer-Tropsch synthesis by the temperature-programmed hydrogen desorption method (TPD H2) were studied. The influence of the polymorph (γ, θ, α) of the support on the physicochemical properties of the Co-Ni / Al2O3 catalyst was studied.
Keywords: Fischer-Tropsch synthesis, biomass, catalyst, support, Ni promoter, polymorphic Al2O3 modifications, TPD H2 method, active surface, dispersity, cobalt crystallites
The parameters of the porous structure and the outer surface of cobalt catalysts for the Fischer-Tropsch synthesis prepared by the water-impregnation method were studied. The effect of the polymorphous modification of the support on the physico-chemical properties of the Co / Al2O3 catalyst was studied.
Keywords: Fischer-Tropsch synthesis, synthetic motor fuel, catalyst, carrier, promoter, polymorphic Al2O3 modifications, elemental analysis, specific surface, porous structure
The parameters of the porous structure and the active surface of cobalt catalysts for the synthesis of liquid and solid hydrocarbons (Fischer-Tropsch synthesis) prepared by the method of impregnating a silicate carrier were studied. The effect of additives of oxide promoters on the specific surface, the volume and size of pores, the dispersion and size of crystallites of metallic cobalt on the surface of the Co / SiO2 catalyst was studied.
Keywords: Fischer-Tropsch synthesis, motor fuel, synthetic hydrocarbons, catalyst, promoter, carrier, specific surface, porous structure, catalytic activity, selectivity
An experimental study of two instances of low-noise amplifiers of the range 1.5-2.0 GHz is carried out. The following results were obtained: the amplification gain varies from 24 to 37 dB in the frequency range; the maximum output power was not less than 10 mW (10 dBm); the compression point of 1 dB is achieved with an input power of minus 16 dBm. To illustrate the measurement results, two amplitude-frequency characteristics and an amplitude characteristic of the second specimen are given. The main element of the studied amplifier is a chip of the type MAAL-007304.
Keywords: Microwave power amplifier, decimeter waves, amplitude-frequency characteristic, experiment, microcircuit
In the present article examples of improvement of ecological indicators in the conditions of dense building of the city are reviewed, the principles of territorial planning are described. Detailed studying of environmental problems of the city, a way of their decision is carried out, the most optimum mechanism of a solution is revealed. This article gives the chance will get acquainted with result of numerous researches in the field of modernization of an ecological framework of the city, the most suitable and elementary actions in the realization increasing the area of city "green zones" in the conditions of dense pointed building are given. Having analysed the studied material, conclusions by the given examples are drawn.
Keywords: ecological equilibrium, the urbanized territory, gardening of the city, vertical gardening, mobile gardening
In article a modelling and experimental survey of the controlled attenuator in a frequency range 2 - 4 GHz is performed. It is received the minimum attenuation no more than 3.5 dB, the maximum attenuation not less than 56 dB at a current 3.8 mA. The amplitude-frequency characteristic unevenness at a current 3.8 mA does not exceed 3 dB. The attenuator design is made in the form of the hybrid module. The attenuator is intended for adjustment of transfer constant of the microwave receiver.
Keywords: attenuator, pin-diode, amplitude-frequency characteristic, control current
We propose a probabilistic and statistical method of estimating parameters of the traction units, which is the creation of acceptable modes of operation taking into account the probabilistic nature of the load, the probability ratios, and other factors that act continuously and systematically change operational characteristics of machine-tractor units. Presents the graphical dependence of the speed of the shaft of the engine SMD-62 degree load and the coefficient of its variation.
Keywords: mathematical expectation, function of communication, frequency of rotation of the motor shaft, the coefficient of variation, the degree of load probability ratio
In the article the analysis of the market of services of a car-care center of an average city is carried out. A selection of popular car repair shops is given. The market is estimated by the number of required posts and the market share of the services in the city.
Keywords: Car, maintenance, repair, market of services of car-care center, working post
The present work is devoted to study of atomic and electronic structure of nitrospiropyran molecules deposited on a Bi (111) substrate before and after irradiation by UV light and X-rays. The study was done using the density functional theory (DFT) and a theoretical analysis of the X-ray absorption fine structure (XAFS) spectroscopy. As a result of the calculations the low-energy structure for nitrospiropyran molecules on a Bi (111) substrate was obtained.
Keywords: local atomic and electronic structure, X-ray absorption spectroscopy, photoisomerization, density functional theory
Correlation intervals of chaotic systems with modulated time step-size signals was estimated. Temporal discretisation step estimation ratio to quasi-resonant period oscillations was varied. Probability distributions of the Lorenz system signals are considered. Discretization step size influence on poly Gauss properties of signals was carried out.
Keywords: dynamic chaos, radioelectronic dynamic systems, statistical properties
Study of stress-strain state of the construction using the Finite Difference Method. Obtained the matrix of coefficients of resolving equations. To assess the convergence of the calculation results were compared with the known numerical solutions.
Keywords: the Finite Difference Method, diagrams of moments, Fixed Offshore Platforms, linear displacement, deflection, thin plates
Paper deals with the analysis and synthesis of geographically distributed systems for storage of hazardous substances from the environmental safety position. Particular attention is paid to the information layer to ensure environmental safety (ES) of these systems, which operates on the results of the processing of regulatory documents, environmental monitoring data, analytical reports, etc. Its operation is based on a system of specialized automated workplaces (AWP), each of which generates a plurality of projections and calculations in order to provide ES, using information on three levels of detail: the physical, technological and logical. The structures of mathematical, informationtion, software and hardware provision of AWP are discussed. It is shown that the proposed AWP structure can be used in the design of the various systems for storage of hazardous substances and is aimed to provide ES in their operation.
Keywords: geographically distributed storage systems, hazardous materials, environmental security, information maintenance, environmental specialists, workstation
The problem of inclusion of children with disabilities in joint training with their peers, its positive impact on children with impaired and regulatory development. The authors of the structure of an inclusive orientation program for preschool children.
Keywords: inclusion, children with disabilities, an inclusive club, eco-culture.
The article deals with the problem of conflict management in the activity of election officials. The authors present the results of a survey of members of precinct election commissions, conflict-free interaction of students at a polling station in the framework of practical training in psychology. Using My Content-analysis of questionnaires election officials the basic psychological characteristics necessary for constructive engagement in conflict situations during the election.
Keywords: conflict, conflict management, conflict prediction, conflict prevention, conflict potential, election officials, constructive cooperation.
The results of experimental studies on the sorption properties of the material ODM - 2F in aluminum, iron and petroleum products
Keywords: Water preparation, filtering material, the sorption isotherm, ODM-2F