In this paper we study of the local atomic and electronic structure of nanostructured condensed material for rechargeable current sources on the basis of 15mas.%V2O5/Fe/LiF nanocomposite within charge-discharge cycle. Principle component analysis (PCA) of the series of Fe K-edge spectra collected during 1 st charge showing the concentrations of the components Fe, FeF2 and V[FeV]O4. We found the changes in the V oxidation state from the analysis of the experimental Fe K- and V K- XANES spectra. Total and partial density of states of components are presented.

Keywords: nanostructured materials for rechargeable current sources, dynamics of local atomic and electronic structures, XANES, DFT

The catalytic activity of Pt/C and PtxNi/C electrocatalysts prepared by  borohydride methode was studed. It was established that the specific activity  of fresh prepared Pt3,7Ni/C  catalyst  in oxygen  electroreduction  reaction is higher in compare with Pt/C material. After treatment of Pt3,7Ni/C material in the hot acid  nickel in the surface layers of nanoparticles was dissolved and the composition of nanoparticles was changed to Pt5,6Ni. The electrochemical surface area of the Pt5,6Ni catalyst and specific activity was slightly decreased after corrosion treatment. 

Keywords: platinum electrocatalysts, corrosion stability of the nanoparticles, fuel cells, X-ray diffraction, borohydride synthesis

The problems of building the architecture and design of the database structure for the storage of the structure of the chemical compounds and their analysis using heuristic algorithms
Proposed the structure of the database that allows you to store information about the structure of chemical compounds with varying degrees of detail. This approach simplifies forming of the structural descriptors used to build models of "structure-property" based on the genetic algorithms.

Keywords: database architecture, chemicals, data mining, heuristics

With the use of pulsed laser deposition and carbothermal synthesis а photosensitive structure on the basis of the Schottky barrier Au/ZnO(nanorods)/ZnO(film)/ZnO(nanorods)/Au was obtained. The parameters of the carbothermal method of synthesis of nanorods ZnO were optimized. Under directly applied bias of 7V current sensitivity of luminous flux for this photodetector is observed in the UV and visible regions of the spectrum, and is 0.14 A/W - for 325 nm and 0.18 A/W - to 405 nm, which means that this structure has the ability of potential applications in various fields for the control of UV radiation (for example, for the monitoring of solar UV radiation, control of UV radiation in air and disinfecting water devices).

Keywords: ZnO nanorods, Schottky barrier, photodetector, photosensitivity

ZnO nanorod arrays have been synthesized on silicon wafers by chemical vapor deposition (CVD) technique with different  temperature modes, without metal catalyst.  With this method   vertically aligned ZnO nanostructures  were grown at the quite low temperatures.  Modification of the method allowed to place silicon substrates in areas with different  ratios of concentrations of the molecules in the vapor phase. Photoluminescence spectroscopy and electron microscopy studies have shown that morphologies and optical properties of nanorods depends on different ratios of concentrations of the molecules in the vapor phase.

Keywords: ZnO nanorods,chemical vapor deposition (CVD), photoluminescence

The arrays of ZnO nanorods were obtained on the sapphire substrates by means of pulsed laser deposition under the high pressure of argon. The conditions of synthesis were optimized, and their influence on the morphology of  ZnO nanostructures were revealed. It is shown that the concentration of oxygen vacancies in ZnO nanorods can be changed by regulation of the synthesis temperature from 850 to 915 °. This process can be controlled by the ratio of intensities of the photoluminescence emission in the visible and ultraviolet regions. So, it allows to create nanostructures for UV photodetectors or chemosensors depending on the temperature choice.

Keywords: ZnO nanorods, laser deposition, PLD, photoluminescence

In this paper the technology of repair of ground water retaining structures soil mixture improved quality with and without soil mixture install.Use soil mixture , improved sharps and ensure the return of ashes (repaired ) slopes and ridge structures of high strength (up to 13-15 MPa) and water resistance , thus increasing the effectiveness and quality of the repair work and increased resistance to the elements of the structures induced defect . The presence of the bran soil mixture not only enhances the strength of 30-40% , but also gives a significant increase in water and frost (20-30 %), which prevent or substantially reduce the infiltration of water through the filtration body water retaining structures , since high strength and frost soil-concrete being laid on a slope ( in the recovery slope failure ) and groove (at soil dumping and capacity to or in excess of the design marks ) will reliably protect the body of the dams ( dams ) of the drawdown , erosion , buckling , suffusion , and other deformities.

Keywords: technology, dribble feed , soil mixture, sift, cement, fly ash, dam, construction and repair operations, soil mixture installation, factors plan of the experiment, the regression equation

In the article authors examine specificities of internal components behavior changing in fiber-optical cable under influence of strong variable uniform electromagnetic field. There are some process variations proposed for describing of obtained results.

Keywords: fiber-optical cable, electrothermal degradation, kevlar, conductivity, open fiber-optical cable, partial discharges, water treeing

The article describes peculiarities of modern syntax parser systems and problems originating in text analysis. As a result of comparative analysis the authors propose a unified approach to processing of unstructured texts in Russian and English which combines morphology and syntax processing. The developed syntax analysis system, using verbs’ valency dictionary, samples of minimal structural schemes of sentences and samples of conjunctions, allows choosing predicative structures of sentences in the text, realizing initial semantic analysis due to semantic content of predicate’s actants and building trees of syntactical subordination of sentences. The derived trees hold elements of tree of constitutives and tree of dependences. The proposed samples and rules organization allows resolving some of the problems of modern parsers. And the use of verbs’ valency dictionary allows reducing the number of sentences syntax analysis variants.

Keywords: automatic text processing; syntax parser; morphological analysis; structural text elements

In this paper is offered hydraulic sensor to measure the kinematic, power and energy parameters. Developed scheme and the principles of the hydraulic sensor.  Identification  on the special flow lab with real modes of the device is determined by its performance in different conditions. Approximation of the results received dependences flow and pressure drop characteristics on the speed and entrance pressure, allowed more correctly assess and describe the operation of the hydraulic sensor over the entire range of speed and entrance pressure.

Keywords: hydraulic sensor, spilling method, flow and pressure drop characteristics, multifunction control unit.

An analysis of the problem of increasing the efficiency of the functioning of the logging trucks for hauling timber to the lower timber depots and consumers. Proposed technical solutions for of raising cross-trains in complex natural and industrial environments.

Keywords: Active semi-trailer used forestry, passableness, prosary operation.

The temperature dependencies of the main parameters of p-channel MOSFET model in a temperature range 20 ... 300 K are measured. The universal formal four-parametric model, which allows approximating all experimental temperature dependencies with the relative error less than 1 % is proposed. The model is intended for the MOSFETs which are applying in low-noise amplifiers of the radio-receiving devices of an optical and infrared range on astronomical satellites, radio telescopes and space observatories. The presented results can be used to simulate the temperature modes of MOSFET amplifiers in SPICE-type electronic simulators. The solution of this problem will predict uptime device when the temperature changes in the cases of emergency or extraordinary situations and also will allow optimizing the choice of refrigerant and increasing the reliability of the amplifier in the conditions of cryogenic temperatures.

Keywords: MOSFET, MOSFET parameters, cryogenic temperature, parameters measurement, temperature dependencies

The method of digital parametric measurement of the phase shift of signals with slowly varying amplitudes of the same slowly varying instantaneous frequencies was proposed. The numerical simulations and experiments on the developed hardware and software system were carried out. The error of measurement the phase difference of harmonic signals in the experiments were not more than  0,00001 radian. The method can be used in applications where the measured value is expressed in terms of the phase difference of quasi-harmonic signals.

Keywords: quasi-harmonic signal, phase shift, real time measurements, hardware and software system

In this paper a systematic study of individual single-walled and multi-walled carbon nanotubes was performed by Raman spectroscopy and high-resolution electron microscopy. We have presented the geometrical and electronic structure analysis on the examples of two tubes: individual single-walled and double-walled nanotubes. The role of different environmental effects and their influence on the final structure assignment are discussed. Moreover, we have shown that the Raman spectroscopy gives reliable estimations of the nanotube diameters and the conductivity. Given a non-destructible character of Raman spectroscopy, we may conclude that it is one of the most efficient methods for structure analysis of carbon nanotubes.

Keywords: Carbon nanotubes, Raman spectroscopy, electron microscopy

Proposed by parallel implementation structures aloritmicheskih simulating year-round circulation of water bodies. The research evaluation of computation time, find the optimal algorithm for the implementation of independent calculations for multi-core processors to reduce the computation time.

Keywords: parallelization of computations, thermohydrodynamics modeling of water objects, multi-core processors